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21.
Due to its harmful impact on human health, the presence of heavy metals, metalloids and other toxic pollutants in drinking or irrigation water is a major concern. Recent studies have proved that nanosized adsorbents are significantly more effective than their microsized counterparts. Particular attention has been given to nanocomposites with nanoadsorbents embedded in matrixes that could provide stability to the material and contribute to eliminating problems that may appear when using conventional granular systems. This study presents the preparation of a novel hybrid filter from a commercially available polypropylene (PP) non-woven fabric matrix modified with multiwall carbon nanotubes (MWCNT) and iron oxy(hydroxide) nanoparticles, and its use in the removal of As(III). A Box–Behnken statistical experimental design has been chosen to explore relevant variables affecting the filter performance: (1) As(III) concentration, (2) pH and (3) sorbent dose. From an As(III) concentration of 10 mg L?1, at pH 6.5 and with a sorbent dose of 5 g L?1, the PP filter modified with MWCNT removes 10% of the initial metalloid concentration, reaching a capacity of 0.27 mg g?1. After modification with iron oxy(hydroxide), the performance of the material is largely enhanced. The filter, under the same conditions, removes 90% of the initial As(III) concentration, reaching a capacity almost tenfold higher (2.54 mg g?1). This work demonstrates that the developed hybrid filter is effective toward the removal of As(III) in a wide range of pHs. A cubic regression model to compute the removal of the filter as a function of pH and sorbent dose is provided.  相似文献   
22.
This paper presents the results of studies on plant macroremains found in the upper Turonian of the Folwark Quarry, Opole, Poland, associated with palynological studies of the host rocks. In addition to a few macrofossils (gymnosperm wood, conifer Geinitzia reichenbachii and fern ?Didymosorus) rich sporomorphs (bryophyte, lycopod and fern spores, conifer and angiosperm pollen grains) and marine palynomorphs (mainly dinoflagellate cysts) were recorded. The palynological analysis revealed that the vegetation on the neighbouring land (the East Sudetic Island) in the late Turonian was much more diverse than could be reconstructed based on only macrofossil remains. The latter are taxonomically restricted and dominated by one gymnosperm species (Geinitzia reichenbachii), which make them similar to most neighbouring, coeval Central European assemblages. Its over representation is, thus, a result of taphonomy.  相似文献   
23.
Mineralogy and Petrology - Mineralized NYF and LCT pegmatites occur throughout the northeast-trending Neoproterozoic Damara Belt, Namibia. Mineralization in the pegmatites varies geographically,...  相似文献   
24.
Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P<0.01O8)·8H2O, accompanied by skutterudite,...  相似文献   
25.
Width of the first ray of the pectoral fin has been measured in two places for 154 young and 89 adult wels. Statistical relationships between the above characters and fish length as well as its maturity and sex have been proved. Three models of discriminant function for identification of adult fish sex have been derived and verified. The accuracy of sex separation has been 89,5% in a standard sample of wels, and 90,6% in a routine sample, after an adjustment in the procedure.  相似文献   
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Some ilmenite concentrates obtained from oleate flotation of ilmenite ores from NE Poland contain less than the required 45% TiO2 due to the presence of green spinels (hercynite and pleonaste). Such concentrates were further upgraded by different separation techniques. It was established at microlaboratory scale that magnetic, gravity and high-tension separations can provide qualified ilmenite concentrates with TiO2 recovery in the order of 50 to 80%.  相似文献   
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Amidst metavolcanic rocks and phyllites of the Góry Kaczawskie region occur isolated carbonate bodies known as the Wojcieszów limestones. The bodies enclosed in the metavolcanites show primary (sedimentary) contacts, while those in the phyllites do not have such contacts. The Wojcieszów limestones and metavolcanic rocks form sequences displaying mutual spatial and genetical relations. Submarine volcanic elevations were covered with chemical and biochemical carbonate precipitation, the intensity of which was stimulated and controlled by the volcanic activity.
Zusammenfassung Inmitten der metavulkanischen Gesteine und Phyllite von Góry Kaczawskie erscheinen isolierte Karbonatgesteinskörper, die als Wojcieszów-Kalke bekannt sind. Die Karbonatgesteine innerhalb der Metavulkanite zeigen sedimentäre Kontakte, während die in den Phylliten eher tektonisch begrenzt sind. So kann man den Wojcieszów-Kalken und den Metavulkaniten eine räumliche und genetische Beziehung zusprechen. Submarine Erhebungen aus Vulkangesteinen waren mit chemischen und biochemisch gefällten Karbonatserien bedeckt, wobei die vulkanische Aktivität die Karbonatbildung unmittelbar beeinflu\te.

Résumé Parmi les métavolcanites et les phyllites de la région du Góry Kaczawskie, il existe des corps carbonatés isolés connus sous le nom de »calcaires de Wojcieszów«. Ceux qui sont inclus dans les métavolcanites présentent des contacts sédimentaires, contrairement à ceux qui sont inclus dans les phyllites, dont les contacts sont tectoniques. Entre les calcaires de Wojcieszów et les roches métavolcaniques, il est donc possible d'établir des relations spatiales et génétiques. Des reliefs volcaniques sous-marins ont été le siège d'une précipitation carbonatée chimique et biochimique dont l'intensité dépendait de l'activité volcanique.

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  相似文献   
30.
We use diagnostic studies of off-line variable infiltration capacity (VIC) model simulations of terrestrial water budgets and 21st-century climate change simulations using the parallel climate model (PCM) to estimate the time required to detect predicted changes in annual precipitation (P), evapotranspiration (E), and discharge (Q) in three sub-basins of the Mississippi River Basin. Time series lengths on the order of 50–350 years are required to detect plausible P, E, and Q trends in the Missouri, Ohio, and Upper Mississippi River basins. Approximately 80–160, 50, and 140–350 years, respectively, are needed to detect the predicted P, E, and Q trends with a high degree of statistical confidence. These detection time estimates are based on conservative statistical criteria (α = 0.05 and β = 0.10) associated with low probability of both detecting a trend when it is not occurring (Type I error) and not detecting a trend when it is occurring (Type II error). The long detection times suggest that global-warming-induced changes in annual basin-wide hydro-climatic variables that may already be occurring in the three basins probably cannot yet be detected at this level of confidence. Furthermore, changes for some variables that may occur within the 21st century might not be detectable for many decades or until the following century – this may or may not be the case for individual recording station data. The long detection times for streamflow result from comparatively low signal-to-noise ratios in the annual time series. Finally, initial estimates suggest that faster detection of acceleration in the hydrological cycle may be possible using seasonal time series of appropriate hydro-climatic variables, rather than annual time series.  相似文献   
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